Sol-gel inks produce complex shapes with nanoscale features
New sol-gel inks developed by researchers at the University of Illinois can be printed into patterns to produce three-dimensional structures of metal oxides with nanoscale features.
The ability to directly pattern functional oxides at the nanoscale opens a new avenue to functional devices. Potential applications include micro-fuel cells, photonic crystals and gas sensors.
The researchers describe the new inks in a paper accepted for publication in the journal Advanced Materials, and featured on its 鈥淎dvances in Advance鈥� Web site.
鈥淯sing this new family of inks, we have produced features as small as 225 nanometers,鈥� said co-author Jennifer Lewis, the Thurnauer Professor of Materials Science and Engineering and director of the university鈥檚 Frederick Seitz Materials Research Laboratory (FSMRL). 鈥淥ur goal is to get down to 100 nanometer feature sizes.鈥�
To create three-dimensional structures, the researchers use a robotic deposition process called direct-write assembly. The concentrated sol-gel ink is dispensed as a filament from a nozzle approximately 1 micron in diameter (about 100 times smaller than a human hair). The ink is dispensed while a computer-controlled micropositioner precisely directs the path. After the pattern for the first layer is complete, the nozzle is raised and another layer is deposited. This process is repeated until the desired shape is produced.
鈥淲e have opened direct ink writing to a new realm of functional materials,鈥� said graduate student Eric Duoss, the paper鈥檚 lead author. 鈥淪ince we print the desired functionality directly, the need for complicated templating and replicating schemes is eliminated.鈥�
Unlike previous inks, which require a liquid coagulation reservoir, the newly formulated inks are concentrated enough to rapidly solidify and maintain their shape in air, even as they span gaps in underlying layers.
鈥淭his gives us the ability to start, stop and reposition the flow of ink repeatedly, providing exquisite control over the deposition process,鈥� Duoss said. 鈥淔or example, we can directly pattern defects in three-dimensional structures for use as photonic crystals.鈥�
After the structures have been assembled, they are converted to the desired functional oxide phase by heating at elevated temperature. Titanium dioxide, which possesses high refractive index and interesting electrical properties, is one material the researchers have successfully produced.
The researchers鈥� ink design and patterning approach can be readily extended to other materials. 鈥淭here are a nearly endless variety of materials to choose from,鈥� Lewis said. 鈥淲e envision having a toolbox of inks that can print at the micro- and nanoscale. These inks will be used for heterogeneous integration with other manufacturing techniques to create complex, functional devices composed of many different materials.鈥�
Source: University of Illinois at Urbana-Champaign
