Chemists discover new way of breaking down climate-damaging 'laughing gas'
Gaby Clark
scientific editor
Robert Egan
associate editor
"Defying climate change calls for new approaches in breaking down greenhouse gases," Professor Jan Paradies of Paderborn University said. The chemist and his team have now moved a step closer to this goal: The scientists have successfully managed to reduce ozone-damaging nitrous oxide ("laughing gas") to its harmless constituent parts using metal-free catalysis at low temperatures. The results are in the Journal of the American Chemical Society.
"Nitrous oxide is one of the most potent ozone-depleting substances and has a global warming potential 265 times higher than that of CO鈧. It causes around 6% of global warming and is used in agricultural, industrial, and medical processes. Its concentration in the atmosphere has risen by 20% since the industrial revolution. Given this environmental impact, there is a pressing need for research into new, efficient reduction methods," Professor Paradies explained.
His research team, consisting of doctoral students Rundong Zhou and Viktorija Medvaric as well as Professor Thomas Werner, have demonstrated a facilitation of the oxygen transfer reaction from nitrous oxide to the phosphetane catalyst. Of the greenhouse gas, this then leaves behind only the harmless nitrogen, which can, for example, be further processed into fertilizer for agriculture. The new phosphetane-oxygen compound can then be returned to its original state via a reaction with a silane (a special chemical compound containing silicon and hydrogen), meaning that it can be repeatedly reused. This creates a catalytic cycle.
More information: Rundong Zhou et al, Metal-Free Reduction of Nitrous Oxide via PIII/PV鈺怬 Cycling: Mechanistic Insights and Catalytic Performance, Journal of the American Chemical Society (2025).
Journal information: Journal of the American Chemical Society
Provided by Paderborn University